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Distribution et role des composes soufres reduits volatils sur la speciation metallique ArchiMer
Cozic, Amandine.
A sensitive, precise and rapid analytical method was elaborated to measure simultaneously 5 volatile reduced sulfur compounds (VRSC) ; hydrogen sulfide (H2S), carbonyl sulfide (OCS), methane thiol (MeSH), dimethyl sulfide (DMS), dimethyl disulfide (DMDS). The study of VRSC in the Bay of Quiberon highlights seasonal and interannual variations of concentrations in epibenthic zone. H2S analyzed near the sediment water interface (anoxic microzones), is more elevated in summer. The OCS distribution is consistent with a predominant photodegradation in winter and a sedimentary source in summer. The variations of MeSH, DMS and DMDS are correlated with the Dinophyceae abundance. In the Seine estuary, the absence of volatile H2S in the up estuary is explained by the...
Tipo: Text Palavras-chave: Phytoplankton; Metal speciation; DMS; Sulfur; Phytoplancton; Spéciation métallique; DMS; Soufre.
Ano: 2007 URL: http://archimer.ifremer.fr/doc/2007/these-2687.pdf
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Impact du sédiment sur les mortalités estivales de naissain d'huîtres creuses Crassostrea gigas en baie de Quiberon ArchiMer
Bedier, Edouard; Knoery, Joel Radford; Fleury, Pierre-gildas; Quiniou, Francoise; Langlade, Aime; Cozic, Amandine; Delesmont, Edith; Delesmont, Régis; Caisey, Xavier; Lecureuil, Laetitia.
The phenomenon of summer mortalities of the Pacific cupped oyster Crassostrea gigas is observed in France since the beginning of the 90's. These mortalities are classically associated to younger stages and summer temperatures and occur during the reproduction period of the animal. The studies undertaken during the project Morest (2001-2005), showed that a number of biological and environmental risks, the interaction of them induces lethal stresses for animals in physiological weakness, exists in summer. Among these risks, that which is withstood by the oysters bred close to the sediment proved to be significant in intertidal areas. In Quiberon bay (southern Brittany, France), the breeding practices of sowing oysters in deep water is thus likely to expose...
Tipo: Text Palavras-chave: Huître; Crassostrea gigas; Mortalité; Sédiment; Composé réduit; Flux; Sulfure; Ammonium; Oyster; Crassostrea gigas; Mortality; Sediment; Reduced compound; Flux; Sulphide; Ammonia.
Ano: 2006 URL: http://archimer.ifremer.fr/doc/00108/21956/19550.pdf
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Interactions between Volatile Reduced Sulfur Compounds and Metals in the Seine Estuary (France) ArchiMer
Cozic, Amandine; Viollier, E; Chiffoleau, Jean-francois; Knoery, Joel; Rozuel, Emmanuelle.
Concentrations of volatile hydrogen sulfide (H2S), carbonyl sulfide (OCS), methane thiol (MeSH), dimethyl sulfide (DMS), and dimethyl disulfide (DMDS) in the Seine estuary (France) were investigated in spring 2005 using samples collected from the first meter beneath the surface. Levels of dissolved metals (Ag, Cd, Cu, Zn, Ni, Co, Pb), suspended particulate matter, and particular organic carbon were also assessed. Maximum concentrations were 0.80 nM for H2S, 0.64 nM for OCS, 3.06 nM for MeSH, 11.06 nM for DMS, and 1.18 nM for DMDS, and different features were observed for the five volatile reduced sulfur compounds (VRSCs). Experiments were conducted to determine silver-VRSC conditional stability constants. Major interactions were observed between H2S and...
Tipo: Text Palavras-chave: Conditional stability constant; Metal; Volatile reduced sulfur compounds; Seine estuary.
Ano: 2008 URL: http://archimer.ifremer.fr/doc/2008/publication-5019.pdf
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